We're joined by the incomparable writer and performer Natalie Walker (Vulture.com, @nwalks on Twitter) to learn a little about... CHEMISTRY (and listen to some essential Brian d'Arcy James).

Each week, our hosts Jimmy Blackmon (Smash viewing veteran) and Marty Scanlon (Smash viewing virgin) are joined by guest luminaries from the world of Broadway, TV, and comedy to celebrate (and at times, just comprehend) NBC’s short-lived musical drama SMASH, episode-by-episode in all its beautiful, arresting, endlessly frustrating, and inspiring glory.

Smash Bros Theme & 'Let Me Be Your (8-Bit) Star' by Marty Scanlon