Postcards from Pearl is the best 1-on-1 actual play I've ever heard. Pearl is a larger-than-life character and there are so many great NPCs I sometimes forget it's just 2 people! Bursting with creative energy and anime-style hijinks, this is one of the best podcasts out there. And my kids love listening with me! I don't think you'll find a better Pokemon-themed podcast you can enjoy together with the whole family!